Yes, you can use XnView to mass watermark photos in a folder.Xnview enable you to mass edit photos.
If you dont have the watermark function, just add it to your Xnview.
1. Scale/Resize the watermark via Percent, Pixels, or "Fit to Image"
2. Invert ("negative image") the watermark image.
3. Use thumbnail label for watermark
4. Save/recall/delete named watermark specification