Click the "Finder" icon in the computer's dock, followed by the "Applications" folder icon. Double-click the "iPhoto" icon to launch the application.
Click the "iPhoto" tab and select the "Preferences..." option from the iPhoto menu.
Click the "Accounts" tab in the Preferences window. Highlight the Facebook account you want to change the login information for in the Accounts pane.
Click the "-" button with the Facebook account highlighted, followed by the "Remove" button to remove the account from iPhoto.
Click the "+" button beneath the Accounts pane. Click the "Facebook" option to highlight it and click the "Add" button to confirm that you want to add a Facebook account to iPhoto.
Type the Facebook login email address and password in the spaces provided. Place a check mark next to the "I agree to Facebook's terms" option, and click the "Login" button. The account with the new login information is added to iPhoto.
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